Fabrication of novel chemosensors composed of rhodamine derivative for the detection of ferric ion and mechanism studies on the interaction between sensor and ferric ion.
نویسندگان
چکیده
Although many rhodamine based fluorescence sensors were reported to detect metal ions with high sensitivity and selectivity, there are very few reports available to study the mechanisms of detection and the interaction between probe and metal ions. This paper aims to detect ferric ions by novel fluorescence chemosensors and study the mechanisms in detail. A novel probe AD-MAH-RhB was designed and synthesized from rhodamine B (RhB), adamantyl (AD), ethylene diamine and maleic anhydride (MAH). AD-MAH-RhB could detect Fe(3+) in aqueous solutions. The mechanism was explored by the HSAB principle, FTIR and mass spectra. The results suggested that Fe(3+) bound with amine and oxygen atoms in AD-MAH-RhB to form a complex composed of a 2 : 1 stoichiometry of Fe(3+) and the probe. Moreover, computational simulations were employed to further investigate the detection mechanism. The calculated results showed that Fe(3+) could conjugate with AD-MAH-RhB probe to form a stable complex, which was induced by synergetic effects of the suitable space and distance of van der Waals forces. However, Hg(2+) was found to disturb this detection and form a complex with 1 : 2 stoichiometry of Hg(2+) and AD-MAH-RhB. Then, another probe, β-cyclodextrin modified polymaleic anhydride (PMAH-CD) including AD-MAH-RhB (PMAH-CD/AD-MAH-RhB) was fabricated by inclusion interaction between CD and AD. PMAH-CD@AD-MAH-RhB showed high selectivity and sensitivity to Fe(3+) in the aqueous solution by eliminating the interruption of Hg(2+) possibly due to the high hydrogen interaction among the probes to inhibit the stable form complex with Hg(2+).
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ورودعنوان ژورنال:
- The Analyst
دوره 140 4 شماره
صفحات -
تاریخ انتشار 2015